| 1 | Forged Carbon Steel Balls | Medium- to high-carbon steel, commonly with carbon content around 0.60%–1.00% | 20–150 mm | Approximately 55–65 HRC at the working surface | About 7.80 g/cm³ | Mining, copper, gold, iron ore, and general-purpose wet grinding | High impact resistance and good resistance to breakage | Surface hardness, core hardness, impact toughness, dimensional tolerance, and quench quality |
| 2 | High-Chromium Cast Balls | Cast iron or steel alloy containing approximately 10%–30% chromium | 25–120 mm | Approximately 58–68 HRC | About 7.40–7.80 g/cm³ | Dry or wet grinding where abrasive wear is dominant | Strong abrasion resistance and reduced ball consumption in suitable mill conditions | Chromium and carbon content, carbide distribution, hardness gradient, porosity, and crack inspection |
| 3 | Low-Chromium Cast Balls | Cast alloy iron with a lower chromium addition, often below 10% | 25–100 mm | Approximately 50–62 HRC | About 7.30–7.70 g/cm³ | Cement, limestone, coal, and moderately abrasive feed materials | Balanced cost, hardness, and impact performance | Microstructure, hardness consistency, casting defects, roundness, and wear test results |
| 4 | High-Manganese Steel Balls | Manganese steel generally containing approximately 10%–14% manganese | 30–150 mm | Typically 180–300 HB initially; surface hardening may occur during impact | About 7.70–7.90 g/cm³ | Applications involving high impact and larger feed particles | Good toughness and resistance to impact-related breakage | Manganese content, heat-treatment condition, impact toughness, work-hardening response, and crack control |
| 5 | Stainless Steel Balls | Martensitic or austenitic stainless steel, selected for corrosion-sensitive processes | 5–100 mm | Approximately 25–60 HRC, depending on grade and treatment | About 7.70–8.00 g/cm³ | Food, pharmaceutical, chemical, pigment, and laboratory grinding | Improved corrosion resistance and lower risk of iron contamination in selected grades | Corrosion resistance, alloy verification, cleanliness, surface finish, and dimensional accuracy |
| 6 | Alumina Ceramic Balls | High-purity aluminum oxide, commonly 85%–99.9% Al₂O₃ | 0.5–100 mm | Approximately 1,500–2,000 HV | About 3.30–3.90 g/cm³ | Mineral processing, ceramics, paints, coatings, and contamination-sensitive grinding | Very low iron contamination and high chemical stability | Alumina purity, water absorption, apparent porosity, crushing strength, roundness, and chipping |
| 7 | Zirconia Ceramic Balls | Stabilized zirconium dioxide, commonly yttria- or ceria-stabilized | 0.1–30 mm | Approximately 1,000–1,400 HV | About 5.80–6.10 g/cm³ | Fine grinding, electronic materials, inks, coatings, and advanced ceramics | High density, high toughness, and efficient fine-particle size reduction | Zirconia content, stabilizer content, density, wear rate, surface finish, and bead size distribution |
| 8 | Silicon Nitride Balls | Reaction-bonded or pressure-sintered silicon nitride ceramic | 1–50 mm | Approximately 1,400–1,700 HV | About 3.10–3.30 g/cm³ | High-purity milling, electronic powders, technical ceramics, and specialty chemicals | Low density, high temperature resistance, and low contamination potential | Density, fracture toughness, porosity, thermal-shock resistance, and dimensional precision |
| 9 | Glass Grinding Beads | Soda-lime or borosilicate glass, selected according to chemical compatibility | 0.5–10 mm | Typically about 500–700 HV | About 2.40–2.60 g/cm³ | Paints, inks, coatings, agricultural chemicals, and low-to-medium energy dispersion | Cost-effective operation and relatively low material contamination | Bead roundness, chemical resistance, breakage rate, size distribution, and surface defects |
| 10 | Tungsten Carbide Balls | Tungsten carbide with a metallic binder, commonly nickel- or cobalt-based | 0.5–50 mm | Approximately 1,200–2,000 HV | About 14.50–15.20 g/cm³ | Very fine grinding of hard minerals, metal powders, and advanced technical materials | Extremely high density and exceptional resistance to severe abrasive wear | Carbide grain size, binder content, density, magnetic properties, porosity, and fracture resistance |